The four allotropic forms of antimony are known as grey, black, yellow, and explosive. The black, yellow, and explosive forms are unstable. Grey, the only stable form of antimony, is what is considered to be ordinary metallic antimony. It is silvery white and exhibits a bluish or purplish luster. Metallic antimony is naturally occurring. However, elemental antimony is rare to the point that it has no practical significance. The atomic weight is 121.75 and its atomic number is 51. The two stable isotopes are Sb121 and Sb123. The smaller isotopes occurs 57.25% of the time while the larger occurs 42.75% of the time. The electron configuration of the outer valence shell is 5s25p3. Antimony’s radius is ~0.150 nm. Finally, the atomic volume of antimony is 18.4 cm3/mol at 25° C.
Friday, March 6, 2009
Metallic Antimony
Elemental antimony is a metalloid meaning that not a true metal nor is it a non-metal. It resembles a metal, but it does not demonstrate the necessary chemical properties to be considered a metal. The other metalloids are boron, silicon, germanium, arsenic, tellurium, and polonium. Antimony is a member of the Nitrogen group or group 15 of the periodic table. Older periodic tables will designate the Nitrogen group as Group V or Group VA. Antimony and arsenic are very similar to each other both in terms of physical properties and chemical properties. The two elements easily dissolve into one another. It is very difficult to separate a mixture of antimony and arsenic by extraction metallurgy.
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